Purely Covalent Molecular Cages and Containers for Guest Encapsulation.

Fecha de publicación: Fecha Ahead of Print:

Autores de IIS La Fe

Participantes ajenos a IIS La Fe

  • Montà-González G
  • Martí-Centelles V

Grupos

Abstract

Cage compounds offer unique binding pockets similar to enzyme-binding sites, which can be customized in terms of size, shape, and functional groups to point toward the cavity and many other parameters. Different synthetic strategies have been developed to create a toolkit of methods that allow preparing tailor-made organic cages for a number of distinct applications, such as gas separation, molecular recognition, molecular encapsulation, hosts for catalysis, etc. These examples show the versatility and high selectivity that can be achieved using cages, which is impossible by employing other molecular systems. This review explores the progress made in the field of fully organic molecular cages and containers by focusing on the properties of the cavity and their application to encapsulate guests.

Datos de la publicación

ISSN/ISSNe:
0009-2665, 1520-6890

Chemical reviews  American Chemical Society

Tipo:
Review
Páginas:
13636-13708
PubMed:
35867555
Factor de Impacto:
18,718 SCImago
Cuartil:
Q1 SCImago

Citas Recibidas en Web of Science: 105

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Keywords

  • POROUS ORGANIC CAGE; BONDED SUPRAMOLECULAR CAPSULES; BENZENE CARBON NANOCAGES; BIS(CROWN ETHER) HOST; SYNTHETIC LECTINS; IMINE CAGES; ONE-POT; SELECTIVE SYNTHESIS; MAGNETIC-RESONANCE; BINDING-PROPERTIES

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